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Potassium abundances in nearby metal-poor stars
Aims.The potassium abundances for 58 metal-poor stars are determinedusing high-resolution spectroscopy. The abundance trends in stars ofdifferent population are discussed. Methods: .All abundanceresults have been derived from NLTE statistical equilibrium calculationsand spectrum synthesis methods. Results: .The NLTE corrections aresignificant (-0.20 to -0.55 dex) and they depend on the effectivetemperatures and surface gravities. The potassium abundances of thindisk, thick disk and halo stars show distinct trends, such as in thecase of the α-elements. [K/Fe] gradually increases with a decreasein [Fe/H] for thin disk stars, [K/Fe] of thick disk stars is nearlyconstant at [K/Fe] ~ +0.30 dex; halo stars also have nearly constantvalues of [K/Fe] ~ +0.20 dex. Conclusions: .The deriveddependence between [K/Fe] and [Fe/H] is in agreement with thetheoretical prediction of published model calculations of the chemicalevolution of the Galaxy. The nearly constant [K/Mg] ratio with smallscatter suggests that the nucleosynthesis of potassium is closelycoupled to the α-elements.

Na, Mg and Al abundances as a population discriminant for nearby metal-poor stars
Aims.Parameters for 55 nearby metal-poor stars are determined usinghigh-resolution spectroscopy. Together with similar data taken from arecent analysis, they are used to show trends of their Galacticevolution with stellar [Fe/H] or [Mg/H] abundances. The separation ofabundance ratios between disk and halo stars is used as a basiccriterion for population membership. Methods.After carefulselection of a clean subsample free of suspected or known binaries andpeculiar stars, abundances of Mg, Na and Al are based on NLTE kineticequilibrium calculations applied to spectrum synthesis methods. Results.The relation between [Na/Mg] and [Fe/H] is a continuousenrichment through all three Galactic populations spanning a range ofvalues between a metal-poor plateau at [ Na/Mg] = -0.7 and solar values.[Al/Mg] displays a step-like difference between stars of the Galactichalo with overline[Al/Mg] ˜ -0.45 and the two disk populations withoverline[Al/Mg] ˜ +0.10. [Al/Mg] ratios, together with the [Mg/Fe]ratios, asymmetric drift velocities V, and stellar evolutionary ages,make possible the individual discrimination between stars of the thickdisk and the halo. At present, this evidence is limited by the smallnumber of stars, and by the theoretical and empirical uncertainties ofstellar age determinations, but it achieves a high significance. Conclusions.While the stellar sample is not complete with respect tospace volume, the resulting abundances indicate the necessity to revisecurrent models of chemical evolution to allow for an adequate productionof Al in early stellar generations.

Fine structure in the phase space distribution of nearby subdwarfs
We analysed the fine structure of the phase space distribution functionof nearby subdwarfs using data extracted from various catalogues.Applying a new search strategy based on Dekker's theory of galacticorbits, we found four overdensely populated regions in phase space.Three of them were correlated with previously known star streams: theHyades-Pleiades and Hercules streams in the thin disk of the Milky Wayand the Arcturus stream in the thick disk. In addition we find evidencefor another stream in the thick disk, which resembles closely theArcturus stream and probably has the same extragalactic origin.

Sulphur abundance in Galactic stars
We investigate sulphur abundance in 74 Galactic stars by using highresolution spectra obtained at ESO VLT and NTT telescopes. For the firsttime the abundances are derived, where possible, from three opticalmultiplets: Mult. 1, 6, and 8. By combining our own measurements withdata in the literature we assemble a sample of 253 stars in themetallicity range -3.2  [Fe/H]  +0.5. Two important features,which could hardly be detected in smaller samples, are obvious from thislarge sample: 1) a sizeable scatter in [S/Fe] ratios around [Fe/H]˜-1; 2) at low metallicities we observe stars with [S/Fe]˜ 0.4, aswell as stars with higher [S/Fe] ratios. The latter do not seem to bekinematically different from the former ones. Whether the latter findingstems from a distinct population of metal-poor stars or simply from anincreased scatter in sulphur abundances remains an open question.

Abundance trends in kinematical groups of the Milky Way's disk
We have compiled a large catalogue of metallicities and abundance ratiosfrom the literature in order to investigate abundance trends of severalalpha and iron peak elements in the thin disk and the thick disk of theGalaxy. The catalogue includes 743 stars with abundances of Fe, O, Mg,Ca, Ti, Si, Na, Ni and Al in the metallicity range -1.30 < [Fe/H]< +0.50. We have checked that systematic differences betweenabundances measured in the different studies were lower than randomerrors before combining them. Accurate distances and proper motions fromHipparcos and radial velocities from several sources have been retreivedfor 639 stars and their velocities (U, V, W) and galactic orbits havebeen computed. Ages of 322 stars have been estimated with a Bayesianmethod of isochrone fitting. Two samples kinematically representative ofthe thin and thick disks have been selected, taking into account theHercules stream which is intermediate in kinematics, but with a probabledynamical origin. Our results show that the two disks are chemicallywell separated, they overlap greatly in metallicity and both showparallel decreasing alpha elements with increasing metallicity, in theinterval -0.80 < [Fe/H] < -0.30. The Mg enhancement with respectto Fe of the thick disk is measured to be 0.14 dex. An even largerenhancement is observed for Al. The thick disk is clearly older than thethin disk with tentative evidence of an AMR over 2-3 Gyr and a hiatus instar formation before the formation of the thin disk. We do not observea vertical gradient in the metallicity of the thick disk. The Herculesstream has properties similar to that of the thin disk, with a widerrange of metallicity. Metal-rich stars assigned to the thick disk andsuper-metal-rich stars assigned to the thin disk appear as outliers inall their properties.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

Improved Astrometry and Photometry for the Luyten Catalog. II. Faint Stars and the Revised Catalog
We complete construction of a catalog containing improved astrometry andnew optical/infrared photometry for the vast majority of NLTT starslying in the overlap of regions covered by POSS I and by the secondincremental Two Micron All Sky Survey (2MASS) release, approximately 44%of the sky. The epoch 2000 positions are typically accurate to 130 mas,the proper motions to 5.5 mas yr-1, and the V-J colors to0.25 mag. Relative proper motions of binary components are measured to 3mas yr-1. The false-identification rate is ~1% for11<~V<~18 and substantially less at brighter magnitudes. Theseimprovements permit the construction of a reduced proper-motion diagramthat, for the first time, allows one to classify NLTT stars intomain-sequence (MS) stars, subdwarfs (SDs), and white dwarfs (WDs). We inturn use this diagram to analyze the properties of both our catalog andthe NLTT catalog on which it is based. In sharp contrast to popularbelief, we find that NLTT incompleteness in the plane is almostcompletely concentrated in MS stars, and that SDs and WDs are detectedalmost uniformly over the sky δ>-33deg. Our catalogwill therefore provide a powerful tool to probe these populationsstatistically, as well as to reliably identify individual SDs and WDs.

Abundances for metal-poor stars with accurate parallaxes. I. Basic data
We present element-to-element abundance ratios measured from highdispersion spectra for 150 field subdwarfs and early subgiants withaccurate Hipparcos parallaxes (errors <20%). For 50 stars new spectrawere obtained with the UVES on Kueyen (VLT UT2), the McDonald 2.7 mtelescope, and SARG at TNG. Additionally, literature equivalent widthswere taken from the works by Nissen & Schuster, Fulbright, andProchaska et al. to complement our data. The whole sample includes boththick disk and halo stars (and a few thin disk stars); most stars havemetallicities in the range -2<[Fe/H]<-0.6. We found our data, thatof Nissen & Schuster, and that of Prochaska to be of comparablequality; results from Fulbright scatter a bit more, but they are stillof very good quality and are extremely useful due to the large size ofhis sample. The results of the present analysis will be used inforthcoming papers to discuss the chemical properties of thedissipational collapse and accretion components of our Galaxy.Based in part on data collected at the European Southern Observatory,Chile, at the MacDonald Observatory, Texas, USA, and at the TelescopioNazionale Galileo, Canary Island, INAF,Italy-Spain.}\fnmsep\thanks{Table 1 is only available in electronic format the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) orvia\resizebox{8.8cm}{2.2mm}htpp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/404/187}

A Survey of Proper-Motion Stars. XVI. Orbital Solutions for 171 Single-lined Spectroscopic Binaries
We report 25,563 radial velocity measurements for 1359 single-linedstars in the Carney-Latham sample of 1464 stars selected for high propermotion. For 171 of these, we present spectroscopic orbital solutions. Wefind no obvious difference between the binary characteristics in thehalo and the disk populations. The observed frequency is the same, andthe period distributions are consistent with the hypothesis that the twosets of binaries were drawn from the same parent population. Thissuggests that metallicity in general, and radiative opacities inparticular, have little influence over the fragmentation process thatleads to short-period binaries. All the binaries with periods shorterthan 10 days have nearly circular orbits, while the binaries withperiods longer than 20 days exhibit a wide range of eccentricities and amedian value of 0.37. For the metal-poor high-velocity halo binaries inour sample, the transition from circular to eccentric orbits appears tooccur at about 20 days, supporting the conclusion that tidalcircularization on the main sequence is important for the oldestbinaries in the Galaxy. Some of the results presented here usedobservations made with the Multiple Mirror Telescope, a joint facilityof the Smithsonian Institution and the University of Arizona.

A search for previously unrecognized metal-poor subdwarfs in the Hipparcos astrometric catalogue
We have identified 317 stars included in the Hipparcos astrometriccatalogue that have parallaxes measured to a precision of better than 15per cent, and the location of which in the(MV,(B-V)T) diagram implies a metallicitycomparable to or less than that of the intermediate-abundance globularcluster M5. We have undertaken an extensive literature search to locateStrömgren, Johnson/Cousins and Walraven photometry for over 120stars. In addition, we present new UBV(RI)C photometry of 201of these candidate halo stars, together with similar data for a further14 known metal-poor subdwarfs. These observations provide the firstextensive data set of RCIC photometry ofmetal-poor, main-sequence stars with well-determined trigonometricparallaxes. Finally, we have obtained intermediate-resolution opticalspectroscopy of 175 stars. 47 stars still lack sufficient supplementaryobservations for population classification; however, we are able toestimate abundances for 270 stars, or over 80 per cent of the sample.The overwhelming majority have near-solar abundance, with theirinclusion in the present sample stemming from errors in the colourslisted in the Hipparcos catalogue. Only 44 stars show consistentevidence of abundances below [Fe/H]=-1.0. Nine are additions to thesmall sample of metal-poor subdwarfs with accurate photometry. Weconsider briefly the implication of these results for clustermain-sequence fitting.

Revised Magnesium Abundances in Galactic Halo and Disk Stars
A differential analysis of the magnesium abundances in 61 F-K dwarfs andsubgiants with metallicities -2.6<[Fe/H]<+0.2 is performed basedon published observational data. Fundamental parameters for 36 stars aredetermined: T eff from V-K and V-R; logg from HIPPARCOS parallaxes, and[Fe/H] and ξt from Fe II lines. The computations allow for non-LTEeffects in the formation of the Mg I lines. For most of the stars, thestandard errors in the Mg abundances do not exceed 0.07 dex. Themetallicity dependence of [Mg/Fe] is analyzed. Magnesium shows aconstant overabundance relative to Fe of 0.46±0.06 dex formetallicities -2.6<[Fe/H]<-0.7 Mg. The Mg overabundance decreasesabruptly to ˜+0.27 dex at [Fe/H]⋍-0.7. At highermetallicities, the Mg abundance smoothly decreases to the solar value at[Fe/H]=0.0. Halo stars with metallicities [Fe/H]<-1.0 exhibit lowerMg overabundances ( ) compared to the [Mg/Fe] values for other starswith similar [Fe/H].

Three-dimensional Spectral Classification of Low-Metallicity Stars Using Artificial Neural Networks
We explore the application of artificial neural networks (ANNs) for theestimation of atmospheric parameters (Teff, logg, and [Fe/H])for Galactic F- and G-type stars. The ANNs are fed withmedium-resolution (Δλ~1-2 Å) non-flux-calibratedspectroscopic observations. From a sample of 279 stars with previoushigh-resolution determinations of metallicity and a set of (external)estimates of temperature and surface gravity, our ANNs are able topredict Teff with an accuracy ofσ(Teff)=135-150 K over the range4250<=Teff<=6500 K, logg with an accuracy ofσ(logg)=0.25-0.30 dex over the range 1.0<=logg<=5.0 dex, and[Fe/H] with an accuracy σ([Fe/H])=0.15-0.20 dex over the range-4.0<=[Fe/H]<=0.3. Such accuracies are competitive with theresults obtained by fine analysis of high-resolution spectra. It isnoteworthy that the ANNs are able to obtain these results withoutconsideration of photometric information for these stars. We have alsoexplored the impact of the signal-to-noise ratio (S/N) on the behaviorof ANNs and conclude that, when analyzed with ANNs trained on spectra ofcommensurate S/N, it is possible to extract physical parameter estimatesof similar accuracy with stellar spectra having S/N as low as 13. Takentogether, these results indicate that the ANN approach should be ofprimary importance for use in present and future large-scalespectroscopic surveys.

Detection of Metal-poor Stars in the Direction of the North Galactic Pole
A simple approach to detecting metal-poor stars is to measure amagnesium index, which depends on the Mg H band plus the three nearby Mgb lines and is derived through intermediate-band interference filters.An empirically established line of demarcation in the Mg index versusB-V diagram separates metal-poor stars from solar-abundance stars. Afurther separation between metal-poor dwarfs and giants depends on B-Vprimarily dwarfs for B-V<0.55, giants for B-V>0.7, with both dwarfsand giants falling in the transition region. For the metal-poor giantsthe distance from the demarcation line correlates well with [Fe/H],permitting estimates of stellar abundances. Stars in two regions on thesky in the vicinity of the north Galactic pole have been observed withsuch a set of filters. Eighteen stars (6% of the population of 299) inthe sample covering the V range 8.7 to 15.6 and 48 stars (31% of thepopulation of 163) in a deeper probe to V=19.9 found through thisprocess are suspected metal-poor stars according to their Mg indices.Twenty-three are specifically deemed giants, with<[Fe/H]><=-1.5.

Lithium abundances for 185 main-sequence stars: Galactic evolution and stellar depletion of lithium
We present a survey of lithium abundances in 185 main-sequence fieldstars with 5600 <~ Teff <~ 6600 K and -1.4 <~ [Fe/H]<~ +0.2 based on new measurements of the equivalent width of thelambda 6708 Li I line in high-resolution spectra of 130 stars and areanalysis of data for 55 stars from Lambert et al. (\cite{Lambert91}).The survey takes advantage of improved photometric and spectroscopicdeterminations of effective temperature and metallicity as well as massand age derived from Hipparcos absolute magnitudes, offering anopportunity to investigate the behaviour of Li as a function of theseparameters. An interesting result from this study is the presence of alarge gap in the log varepsilon (Li) - Teff plane, whichdistinguishes ``Li-dip'' stars like those first identified in the Hyadescluster by Boesgaard & Tripicco (\cite{Boesgaard86}) from otherstars with a much higher Li abundance. The Li-dip stars concentrate on acertain mass, which decreases with metallicity from about 1.4Msun at solar metallicity to 1.1 Msun at [Fe/H] =~-1.0. Excluding the Li-dip stars and a small group of lower mass starswith Teff < 5900 K and log varepsilon (Li) < 1.5, theremaining stars, when divided into four metallicity groups, may show acorrelation between Li abundance and stellar mass. The dispersion aroundthe log varepsilon (Li)-mass relation is about 0.2 dex below [Fe/H] =~-0.4 and 0.3 dex above this metallicity, which cannot be explained byobservational errors or differences in metallicity. Furthermore, thereis no correlation between the residuals of the log varepsilon (Li)-massrelations and stellar age, which ranges from 1.5 Gyr to about 15 Gyr.This suggests that Li depletion occurs early in stellar life and thatparameters other than stellar mass and metallicity affect the degree ofdepletion, e.g. initial rotation velocity and/or the rate of angularmomentum loss. It cannot be excluded, however, that a cosmic scatter ofthe Li abundance in the Galaxy at a given metallicity contributes to thedispersion in Li abundance. These problems make it difficult todetermine the Galactic evolution of Li from the data, but a comparisonof the upper envelope of the distribution of stars in the log varepsilon(Li) - [Fe/H] plane with recent Galactic evolutionary models by Romanoet al. (\cite{Romano99}) suggests that novae are a major source for theLi production in the Galactic disk; their occurrence seems to be theexplanation for the steep increase of Li abundance at [Fe/H] =~ -0.4.Based on observations carried out at Beijing Astronomical Observatory(Xinglong, PR China) and European Southern Observatory, La Silla, Chile.Table 1 is only available in electronic form at the CDS via anonymousftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/371/943 and athttp://www.edpsciences.org

Non-LTE Abundances and Consequences for the Evolution of the α-Elements in the Galaxy
Abundances of α-elements such as Ca and Mg in disk and halo starsare usually derived from equivalent width lines measured onhigh-resolution spectra and assuming local thermodynamic equilibrium(LTE). In this paper, we present non-LTE differential abundances derivedby computing the statistical equilibrium of Ca I and Mg I atoms, usinghigh-resolution equivalent widths available in the literature for 252dwarf to subgiant stars. These non-LTE abundances, combined with recentdetermination of non-LTE abundances of iron, seem to remove thedispersion of the [Ca/Fe] and [Mg/Fe] ratios in the galactic halo anddisk phases, revealing new and surprising structures. These results haveimportant consequences for chemical evolution models of the Galaxy. Inaddition, non-LTE abundance ratios for stars belonging to the M92cluster apparently have the same behavior. More high-resolutionobservations, mainly of globular clusters, are urgently needed toconfirm our results.

The Galactic Thick Disk Stellar Abundances
We present first results from a program to measure the chemicalabundances of a large (N>30) sample of thick disk stars with theprincipal goal of investigating the formation history of the Galacticthick disk. We have obtained high-resolution, high signal-to-noisespectra of 10 thick disk stars with the HIRES spectrograph on the 10 mKeck I telescope. Our analysis confirms previous studies of O and Mg inthe thick disk stars, which reported enhancements in excess of the thindisk population. Furthermore, the observations of Si, Ca, Ti, Mn, Co, V,Zn, Al, and Eu all argue that the thick disk population has a distinctchemical history from the thin disk. With the exception of V and Co, thethick disk abundance patterns match or tend toward the values observedfor halo stars with [Fe/H]~-1. This suggests that the thick disk starshad a chemical enrichment history similar to the metal-rich halo stars.With the possible exception of Si, the thick disk abundance patterns arein excellent agreement with the chemical abundances observed in themetal-poor bulge stars, suggesting the two populations formed from thesame gas reservoir at a common epoch. The principal results of ouranalysis are as follows. (1) All 10 stars exhibit enhanced α/Feratios with O, Si, and Ca showing tentative trends of decreasingoverabundances with increasing [Fe/H]. In contrast, the Mg and Tienhancements are constant. (2) The light elements Na and Al are enhancedin these stars. (3) With the exception of Ni, Cr, and possibly Cu, theiron-peak elements show significant departures from the solarabundances. The stars are deficient in Mn, but overabundant in V, Co,Sc, and Zn. (4) The heavy elements Ba and Y are consistent with solarabundances, but Eu is significantly enhanced. If the trends ofdecreasing O, Si, and Ca with increasing [Fe/H] are explained by theonset of Type Ia SN, then the thick disk stars formed over the course of>~1 Gyr. We argue that this formation time-scale would rule out mostdissipational collapse scenarios for the formation of the thick disk.Models which consider the heating of an initial thin disk-either through``gradual'' heating mechanisms or a sudden merger event-are favored.These observations provide new tests of theories of nucleosynthesis inthe early universe. In particular, the enhancements of Sc, V, Co, and Znmay imply overproduction during an enhanced α-rich freeze outfueled by neutrino-driven winds. Meanwhile, the conflicting trends forMg, Ti, Ca, Si, and O pose a difficult challenge to our currentunderstanding of nucleosynthesis in Type Ia and Type II SN. The Ba/Euratios favor r-process dominated enrichment for the heavy elements,consistent with the ages (tage>10 Gyr) expected for thesestars. Finally, we discuss the impact of the thick disk abundances oninterpretations of the abundance patterns of the damped Lyαsystems. The observations of mildly enhanced Zn/Fe imply aninterpretation for the damped systems which includes a dust depletionpattern on top of a Type II SN enrichment pattern. We also argue thatthe S/Zn ratio is not a good indicator of nucleosynthetic processes.

Sc and Mn abundances in disk and metal-rich halo stars
Sc and Mn abundances are determined for 119 F and G main-sequence starswith -1.4 < [Fe/H] < +0.1, representing stars from the thin disk,the thick disk and the halo. The results indicate that Sc behaves likean alpha element, showing a decreasing [Sc/Fe] with increasingmetallicity in disk stars and a dual pattern in the kinematicallyselected halo stars. In contrast, Mn shows an increase from [Mn/Fe] =~-0.5 at [Fe/H] = -1.4 to zero at solar metallicity. There appears to bea discontinuity or sharp increase of [Mn/Fe] at [Fe/H] =~ -0.7corresponding to the transition between the thick and the thin disk. Itis discussed if supernovae of Type Ia are a major source of Mn in theGalactic disk or if the trend of [Mn/Fe] vs. [Fe/H] can be explained bynucleosynthesis in Type II supernovae with a strong metallicitydependence of the yield. Based on observations carried out at theEuropean Southern Observatory, La Silla, Chile, and Beijing AstronomicalObservatory, Xinglong, China

Estimation of Stellar Metal Abundance. II. A Recalibration of the Ca II K Technique, and the Autocorrelation Function Method
We have recalibrated a method for the estimation of stellar metalabundance, parameterized as [Fe/H], based on medium-resolution (1-2Å) optical spectra (the majority of which cover the wavelengthrange 3700-4500 Å). The equivalent width of the Ca II K line (3933Å) as a function of [Fe/H] and broadband B-V color, as predictedfrom spectrum synthesis and model atmosphere calculations, is comparedwith observations of 551 stars with high-resolution abundances availablefrom the literature (a sevenfold increase in the number of calibrationstars that were previously available). A second method, based on theFourier autocorrelation function technique first described by Ratnatunga& Freeman, is used to provide an independent estimate of [Fe/H], ascalibrated by comparison with 405 standard-star abundances.Metallicities based on a combination of the two techniques for dwarfsand giants in the color range 0.30<=(B-V)_0<=1.2 exhibit anexternal 1 sigma scatter of approximately 0.10-0.20 dex over theabundance range -4.0<=[Fe/H]<=0.5. Particular attention has beengiven to the determination of abundance estimates at the metal-rich endof the calibration, where our previous attempt suffered from aconsiderable zero-point offset. Radial velocities, accurate toapproximately 10 km s^-1, are reported for all 551 calibration stars.

Towards a fundamental calibration of stellar parameters of A, F, G, K dwarfs and giants
I report on the implementation of the empirical surface brightnesstechnique using the near-infrared Johnson broadband { (V-K)} colour assuitable sampling observable aimed at providing accurate effectivetemperatures of 537 dwarfs and giants of A-F-G-K spectral-type selectedfor a flux calibration of the Infrared Space Observatory (ISO). Thesurface brightness-colour correlation is carefully calibrated using aset of high-precision angular diameters measured by moderninterferometry techniques. The stellar sizes predicted by thiscorrelation are then combined with the bolometric flux measurementsavailable for a subset of 327 ISO standard stars in order to determineone-dimensional { (T, V-K)} temperature scales of dwarfs and giants. Theresulting very tight relationships show an intrinsic scatter induced byobservational photometry and bolometric flux measurements well below thetarget accuracy of +/- 1 % required for temperature determinations ofthe ISO standards. Major improvements related to the actual directcalibration are the high-precision broadband { K} magnitudes obtainedfor this purpose and the use of Hipparcos parallaxes for dereddeningphotometric data. The temperature scale of F-G-K dwarfs shows thesmallest random errors closely consistent with those affecting theobservational photometry alone, indicating a negligible contributionfrom the component due to the bolometric flux measurements despite thewide range in metallicity for these stars. A more detailed analysisusing a subset of selected dwarfs with large metallicity gradientsstrongly supports the actual bolometric fluxes as being practicallyunaffected by the metallicity of field stars, in contrast with recentresults claiming somewhat significant effects. The temperature scale ofF-G-K giants is affected by random errors much larger than those ofdwarfs, indicating that most of the relevant component of the scattercomes from the bolometric flux measurements. Since the giants have smallmetallicities, only gravity effects become likely responsible for theincreased level of scatter. The empirical stellar temperatures withsmall model-dependent corrections are compared with the semiempiricaldata by the Infrared Flux Method (IRFM) using the large sample of 327comparison stars. One major achievement is that all empirical andsemiempirical temperature estimates of F-G-K giants and dwarfs are foundto be closely consistent between each other to within +/- 1 %. However,there is also evidence for somewhat significant differential effects.These include an average systematic shift of (2.33 +/- 0.13) % affectingthe A-type stars, the semiempirical estimates being too low by thisamount, and an additional component of scatter as significant as +/- 1 %affecting all the comparison stars. The systematic effect confirms theresults from other investigations and indicates that previousdiscrepancies in applying the IRFM to A-type stars are not yet removedby using new LTE line-blanketed model atmospheres along with the updatedabsolute flux calibration, whereas the additional random component isfound to disappear in a broadband version of the IRFM using an infraredreference flux derived from wide rather than narrow band photometricdata. Table 1 and 2 are only available in the electronic form of thispaper

Chemical composition of halo and disk stars with overlapping metallicities.
High resolution (R=60000), high S/N spectra have been obtained for 13halo stars and 16 disk stars with 5400<~T_eff_<~6500K,4.0<~logg<~4.6 and overlapping metallicities in the range-1.3<~[Fe/H]<~-0.5. Equivalent widths of weak FeI and FeII linesare used to determine differential values of T_eff_ and logg. Relativeabundances of O, Na, Mg, Si, Ca, Ti, Cr, Fe, Ni, Y and Ba are determinedto a precision ranging from 0.02 to 0.07dex. Kinematical data have beencollected and used to calculate the stellar orbital parameters, R_max_,the maximum distance from the Galactic center, and z_max_, the maximumdistance from the Galactic plane. A group of 8 halo stars havesignificantly lower [α/Fe] values than disk stars of the samemetallicity (α= O, Mg, Si, Ca or Ti). These stars are alsounderabundant in Na and Ni and maybe in Cr. [Na/Fe] ranges from -0.4 to+0.1, and [Ni/Fe] is surprisingly well correlated with [Na/Fe]. Thesmallest values of [α/Fe] and [Na/Fe] are found for the stars withthe largest values of R_max_ and z_max_. This may indicate that theanomalous halo stars have been accreted from dwarf galaxies with achemical evolution history different from that of the inner halo and thedisk. In any case the data show that abundance ratios in stars are notuniversal functions of [Fe/H] and that the chemical evolution of theGalaxy at [Fe/H]=~-1.0 is more complicated than assumed in many models.One halo star, HD 106038, is found to be strongly overabundant in Si,Ni, Y and Ba relative to Fe.

Determination of effective temperatures for an extended sample of dwarfs and subdwarfs (F0-K5).
We have applied the InfraRed Flux Method (IRFM) to a sample of 475dwarfs and subdwarfs in order to derive their effective temperatureswith a mean accuracy of about 1.5%. We have used the new homogeneousgrid of theoretical model atmosphere flux distributions developed byKurucz (1991, 1993) for the application of the IRFM. The atmosphericparameters of the stars cover, roughly, the ranges:3500K<=T_eff_<=8000K -3.5<=[Fe/H]<=+0.53.5<=log(g)<=5. The monocromatic infrared fluxes at the continuum,and the bolometric fluxes are derived using recent results, whichsatisfy the accuracy requeriments of the work. Photometric calibrationshave been revised and applied to estimate metallicities, although directspectroscopic determinations were preferred when available. The adoptedinfrared absolute flux calibration, based on direct optical measurementsof angular stellar diameters, sets the effective temperatures determinedusing the IRFM on the same scale than those obtained by direct methods.We derive three temperatures, T_J_, T_H_ and T_K_, for each star usingthe monochromatic fluxes at different infrared wavelengths in thephotometric bands J, H, and K. They show good consistency over 4000 K,and no trend with wavelength may be appreciated. We provide a detaileddescription of the steps followed for the application of the IRFM, aswell as the sources of the errors associated to the different inputs ofthe method, and their transmission into the final temperatures. We alsoprovide comparison with previous works.

A survey of proper motion stars. 12: an expanded sample
We report new photometry and radial velocities for almost 500 stars fromthe Lowell Proper Motion Catalog. We combine these results with ourprior sample and rederive stellar temperatures based on the photometry,reddening, metallicities (using chi squared matching of our 22,500 lowSignal to Noise (S/N) high resolution echelle spectra with a grid ofsynthetic spectra), distances, space motions, and Galactic orbitalparameters for 1269 (kinematics) and 1261 (metallicity) of the 1464stars in the complete survey. The frequency of spectroscopic binariesfor the metal-poor ((m/H) less than or equal to -1.2) stars with periodsshorter than 3000 days is at least 15%. The spectroscopic binaryfrequency for metal-rich stars ((m/H) greater than -0.5) appears to belower, about 9%, but this may be a selection effect. We also discussspecial classes of stars, including treatment of the double-linedspectroscopic binaries, and identification of subgiants. Four possiblenew members of the class of field blue stragglers are noted. We pointout the detection of three possible new white dwarfs, six broad-lined(binary) systems, and discuss briefly the three already knownnitrogen-rich halo dwarfs. The primary result of this paper will beavailable on CD-ROM, in the form of a much larger table.

Broad band JHK infrared photometry of an extended sample of late type dwarfs and subdwarfs.
The results of a long term programme of broad band JHK photometry, for asample of 360 late type stars, made at the Observatorio del Teide(Tenerife, Spain) are presented. Transformations between thesemagnitudes and those of several currently used systems (CIT (Elias etal. 1982 and Carney 1983), Johnson (Johnson 1966, and Lee 1970), and ESO(Bouchet et al. 1991)) are proposed. A comparison to the narrow-bandsystem of Selby et al. (1988) has been made, in order to check theaccuracy of the photometric system. A mean internal accuracy better than0.02mag in the three bands can be inferred from the comparison to thelarge number of stars in common with Carney (1983), and from thedispersion of the multiple measured stars. The list of standards, thefilter passbands and effective wavelengths, together with correlationsbetween the extinction coefficients, ultimately characterize thephotometric IR system of the Observatorio del Teide (TCS). Data ofcomparable quality previously published have been added in order tocomplete the sample. This way the final sample consists of 550 stars.From the analysis of optical and IR colour:colour diagrams, we maydeduce that the range F0-K0 is properly sampled for0.1>[Fe/H]>-3.0. In the range K0-M4, no reliable photometricestimates of metallicity can be assigned, and only a small number ofstars have spectroscopic determination of the metallicity. Nevertheless,after kinematical considerations, the stars in this spectral range arealso expected to sample the galactic populations of dwarfs. Themetallicity effects on the IR and optical colour:colour diagrams arebriefly discussed.

Subdwarf studies. II - Abundances and kinematics from medium resolution spectra. III - The halo metallicity distribution
Stars previously identified as having UV excesses are observed at 1-Aresolution in the Ca II K-line region. Comparisons of these data withother samples and with Monte Carlo simulations involving a singlecomponent halo have yielded estimates of halo velocity dispersions androtation velocity, corrected for the kinematic biases in the sample. Itis suggested that the data are not consistent with a model in which thehalo formed from star formation in a dissipating, collapsing cloud; theyare, however, reconcilable with the formation of the halo stars bynumerous, independently evolving gas clouds. The metallicitydistribution of a sample of 372 kinematically selected halo stars isthen constructed, with a view to selection effects in the data. Goodagreement is noted between the globular cluster metallicity distributionand a stochastic model with a mean of 10 enrichments/fragment.

A survey of proper motion stars. IX - The galactic halo's metallicity gradient
Using data already presented for a survey of proper motion stars and theBahcall, Schmidt, and Soneira (1983) model of the Galaxy, Galacticorbital parameters are computed, including planar and three-dimensionaleccentricities, apo- and perigalacticon distances, and maximum distancesreached above/below the plane, based on extreme values for R and theabsolute value of Z over 15 azimuthal periods. The orbital data are usedto bin the survey's stars by apogalacticon and maximum Z distances. Inan attempt to isolate a halo population sample, analyses are restrictedto those stars that lag behind the local standard of the rest's circularorbital velocity by 50, 100, 150, and 200 km/s. The mean metallicitiesof the stars in a variety of Rapo and Zmax bins are compared .

A survey of proper-motion stars. III - Reddenings, distances, and metallicities
Further data on the Lowell proper-motion stars surveyed by Carney andLatham (1987) are presented. Both new and published photometry aresummarized for 286 of these stars. Included are R-I data for 64 stars,uvby (or by) data for 221 stars (of which are included new results for152 stars), and JHK (or K) data for 238 stars (of which are included newresults for 180 stars). The procedures used to estimate the reddeningand photometric parallax of each star are discussed. The metallicitiesfor 818 stars, based on 5795 spectra, determined using a new method,described in an earlier paper, which compares synthetic spectra to thelow-signal-to-noise spectra obtained for radial velocities are alsopresented. The reddening, distance, and metallicity are interdependentand have been determined in a self-consistent manner.

Four-color UVBY and H-beta photometry of high-velocity and metal-poor stars. I - The catalogue of observations
A catalog of four-color uvby and H-beta photometry for 711 high-velocityand metal-poor stars is given. The selection of the stars and theobserving and reduction techniques used to obtain these data arediscussed. The photometry has been transformed closely onto the standarduvby-beta system. The errors of the data have been estimated using bothinternal and external comparisons. The data are uniform over the sky;that is, there are no significant north-south differences. For the largemajority of stars the mean errors of V, m1, c1, and beta are less than +or - 0.008 mag, and the error of b-y is less than + or - 0.005 mag.Values of V, b-y and beta and rough photometric classifications aregiven for 63 red and/or evolved stars that fall outside the range of thephotometric transformations.

Carbon and nitrogen abundances in metal-poor dwarfs of the solar neighborhood
Intermediate-resolution C, N, and Fe abundance spectra for 83 subdwarfsin the lowest metallicity range (-1.5 to -3.2), obtained with the LickObservatory 3.1-m Shane telescope, are analyzed. The effects ofsubgiants and binaries on the sample are examined. The relation between(B-V) and (V-K) and effective temperature is studied. C/Fe, N/Fe, andFe/H abundances were determined using the model-atmosphere technique ofspectrum synthesis. The derived abundance values are compared with datafrom previous investigations. It is observed that there is goodcorrelation between the Fe/H abundance values derived from theintermediate-resolution spectra and those based on high-resolutionspectra; C/Fe abundance values are constant; and there is an upturn inthe C/Fe abundance values at the very lowest metallicities.

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